Good move on the ATC head. The four valve XR200R was a two-year only deal, and it was a failure.
https://en.wikipedia.org/wiki/Honda_XR_series
14.7:1 is the stoichiometrically ideal ratio, but not necessarily where max power is created. I suspect that if you dyno tuned it with an O2 sensor, you'd find max power in the 13's or 12's. In general terms, the higher the number, the more heat.